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POLYSTYRENE IODOSOACETATE

CAS No.: 36290-94-5

Formula: C12H13IO4

Molecular Weight: 348.14

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What is POLYSTYRENE IODOSOACETATE

**Introduction to Polystyrene Iodosacetate** Polystyrene iodosacetate is a versatile polymeric reagent widely used in organic synthesis, particularly for oxidation reactions. This stable, insoluble resin combines the robust framework of polystyrene with the oxidative properties of iodosyl acetate, making it an efficient and recyclable alternative to traditional oxidants. It is commonly employed in the selective oxidation of alcohols to carbonyl compounds, sulfides to sulfoxides, and other functional group transformations. Its heterogeneous nature allows for easy separation from reaction mixtures, simplifying purification and reducing waste. With excellent stability and reusability, polystyrene iodosacetate is a valuable tool in green chemistry, offering both efficiency and environmental benefits in synthetic applications.

Preparation Process: To prepare **polystyrene iodosacetate**, follow these steps: 1. **Chloromethylation**: React polystyrene beads with chloromethyl methyl ether and a Lewis acid (e.g., SnCl₄) to form chloromethylated polystyrene. 2. **Azide Formation**: Treat chloromethylated polystyrene with sodium azide (NaN₃) in DMF to convert –CH₂Cl to –CH₂N₃. 3. **Reduction**: Reduce the azide (–CH₂N₃) to amine (–CH₂NH₂) using LiAlH₄ or hydrogenation (Pd/C). 4. **Diazotization & Iodination**: React the amine with NaNO₂/HCl to form a diazonium salt, then treat with KI to yield –CH₂I. 5. **Oxidation**: Oxidize –CH₂I with peracetic acid (CH₃CO₃H) to form –CH₂IO₂ (iodosoacetate). Purify by washing with solvents (e.g., DMF, water, methanol).

Usage Scenarios: Polystyrene iodosacetate is primarily used as an oxidizing agent in organic synthesis, particularly for the selective oxidation of alcohols to aldehydes or ketones. Its polymer-supported structure allows for easy separation and recycling, making it advantageous in green chemistry applications. The compound is also employed in heterogeneous catalysis, facilitating reactions under mild conditions with high efficiency. Additionally, it serves as a reagent in the preparation of iodonium salts and other iodine-containing intermediates. Its stability and insolubility in common solvents make it suitable for use in flow chemistry systems, enabling continuous and scalable oxidation processes in pharmaceutical and fine chemical industries.

POLYSTYRENE IODOSOACETATE Basic Info

Chemical Name POLYSTYRENE IODOSOACETATE

Synonyms PSDIB;CL053;Polystyrene Iodosoacete;POLYSTYRENE IODOSOACETATE;y[4-(diacetoxyiodo)styrene];POLY[4-(DIACETOXYIODO)STYRENE];Polystyrene Iodosoacetate PSDIB;polystyrene supported iodobenzene diacetate;Bis(acetato-O)(4-ethenylphenyl)iodine homopolymer

CAS No. 36290-94-5

Molecular Formula C12H13IO4

Molecular Weight 348.14

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HS Code 2931.90.6000

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POLYSTYRENE IODOSOACETATE Price

Here is a rough price range for "POLYSTYRENE IODOSOACETATE" in the 18 countries listed. Note that this is a highly specialized chemical, and prices may vary significantly based on supplier, quantity, and purity. If no specific data is available, it is marked as "No results."

1. **United States**: $200 - $500 per gram
2. **China**: $150 - $400 per gram
3. **Russia**: No results
4. **Germany**: $250 - $600 per gram
5. **India**: $100 - $300 per gram
6. **Japan**: $300 - $700 per gram
7. **Brazil**: No results
8. **South Korea**: $200 - $500 per gram
9. **Philippines**: No results
10. **United Kingdom**: $250 - $600 per gram
11. **France**: $250 - $600 per gram
12. **Mexico**: No results
13. **Canada**: $200 - $500 per gram
14. **South Africa**: No results
15. **Egypt**: No results
16. **Turkey**: No results
17. **Thailand**: No results
18. **Indonesia**: No results

These ranges are approximate and based on general market trends for specialized chemicals. Availability and pricing can vary widely depending on the supplier and region.